The heat for this volcanism comes from the special position of Io relative to Jupiter and the other moons. Io is a small moon, very close to Jupiter, and well inside the other 3 main moons. Io feels the gravitational pull first of Jupiter, then of the outside moons when they sweep by. The alternating pull of gravity has a push-me, pull-me effect on Io, which deforms the moon, and warms it just the way a coat hanger warms when you bend it first one way, then the other way. Due to this warming, Io has many volcanoes.
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